Journal of the Ceramic Society of Japan
Online ISSN : 1348-6535
Print ISSN : 1882-0743
ISSN-L : 1348-6535
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Lead-free Li-modified (Na,K)NbO3 piezoelectric ceramics fabricated by two-step sintering method
Kensuke KATOKen-ichi KAKIMOTOKeiichi HATANOKeisuke KOBAYASHIYutaka DOSHIDA
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2014 Volume 122 Issue 1426 Pages 460-463

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Abstract

Two-step sintering method has been applied to (Li0.06Na0.47K0.47)NbO3 (LNKN) ceramics in order to obtain a homogenous microstructure and high density (96.1% TD). The effects of the sintering temperature on the microstructure and electrical properties of LNKN ceramics were investigated. The two-step sintering has provided better densification at relatively lower temperature (≦950°C) than that of one-step sintering (1082°C), which suppresses the abnormal grain growth. In addition, the more homogeneous microstructure has been obtained by two-step sintering. The measured dielectric constant, dielectric loss and Curie temperature of the sample for two-step sintering were 666, 2.0% and 454°C, respectively, similar to the values obtained with one-step sintering. Nevertheless, LNKN ceramics prepared by two-step sintering showed higher coercive electric field (=18.8 kV/cm) than that revealed by one-step sintering (=13.0 kV/cm).

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© 2014 The Ceramic Society of Japan
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